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Evaporation-driven spontaneous capillary flow presents a promising approach for driving electrolytes through electrically charged channels and pores in electrokinetic energy conversion devices. However, there are no literature reports of detailed flow visualization in these systems and/or experimental observations relating the liquid velocity and evaporation rate to the generated voltage and current. In this manuscript, we describe such a visualization study for a glass channel based electrokinetic energy conversion device with one of its channel terminals left open to ambient air for facilitating the evaporation process. Fluorescence microscopy was used to measure the liquid velocity in the electrokinetic energy conversion channel by observing the advancement of an electrolyte solution dyed with a neutral tracer. The accumulation of the same dye tracer was also imaged at the open terminal of this glass conduit to estimate the rate of solvent evaporation, which was found to be consistent with the flow velocity measurements. Additionally, an electrochemical analyzer was employed to record the electrical voltage and current produced by the device under different operating conditions. The highest electrical power output was derived in our experiments upon flowing de-ionized water through a 1 μm deep channel, which also produced the fastest liquid velocity in it. Moreover, the energy conversion efficiency of our device was observed to increase for shallower channels and lower ionic strength electrolytes, consistent with previous literature reports on electrokinetic energy conversion platforms.